Got an HTC Vive myself, and yeah the cables and suchlike are a bit of a nuisance. BUT...
...it's
fucking amazing!
I'm currently enjoying The Lab from Valve - as with most of the best VR it's essentially a bunch of tech demos, but bloody good ones. Very much recommended.
Moss is a beautiful platformer that has been developed just for VR, where you control a mouse who has a sword. Very much recommended.
Google Earth goes without saying. Not brilliant, but bloody good.
And the Nvidia Funhouse is OK too, but again is essentially a tech demo.
Things that you think would work perfectly, like Skyrim and Fallout, actually tend to be a bit shonky IMO.